Introductory Concepts in Thermodynamics:
Review and further implications of the First Law of Thermodynamics. State properties. Reversibility and irreversibility. Phase rules. Thermodynamic relationships for a perfect gas.
The Second Law of Thermodynamics:
The development of the 2nd Law. Heat engines and cyclic processes. Calculation of heat and work flows in heat engines and simple thermodynamic cycles. Entropy and irreversible processes.
Practical Thermodynamics Processes and Cycles:
Steam power plant. Gas turbine power plant. Internal combustion engine, Otto and Diesel cycle. Refrigeration and liquefaction.
PVT of Gases, Work Functions, the Thermodynamic Network:
The PVT behaviour of fluids, equations of state, ideal gas. Generalised correlation for gas and the compressibility factor, cubic equations of state. Gibb’s energy, the work functions, and Clausius inequality, and the relationships between thermodynamic state properties.
Phase Equilibria of Pure Substances:
The criteria of equilibria, chemical potential. Thermodynamics of pure substances, the Clapeyron equation, solid liquid, and other phase equilibria. Relationship between Gibb’s Energy, P, T, and fugacity.
Phase Equilibria of Mixtures:
Fundamental property relationships for mixtures and solutions. Raoult’s law, Henry’s law and ideal behaviour. Partial properties, fugacity and fugacity coefficients of pure substances and substances in solutions. Activity coefficients and their determination. Application of phase equilibria for vapour liquid equilibria, total pressure, azeotropes, multi component, vapour liquid equilibria, and prediction of solution behaviour.
Chemical Equilibria:
Generalised stoichiometry, conditions of equilibria in reacting systems and the interrelationship between standard Gibb’s energy change. The effect of temperature on equilibrium constant and the evaluation of equilibrium constants. Relevant Gibb’s energy functions, homogeneous & heterogeneous reaction equilibrium compositions, multi component equilibria.